Chemical biochemical and engineering thermodynamics solution manual

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(a)

Thermostatic bath (surroundings) kept at temperature T compels its temperature (T) on the device.

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So, the constraint inserted in the equilibrium state of the system is temperature.


(b)

Volume of the system need to be constant as it is enclosed in a constant-volume container.

Mechanical isolation requires no work flow and also thermal isolation suggests no warmth circulation in between the mechanism and surroundings.

Therefore, energy of the system such as inner power and enthalpy is likewise consistent.


(c)

Tright here is no circulation of heat because system is thermally isolated from the surroundings.

Because of this, the push of the mechanism must be equal to the pressure exerted on it and ambient pressure by the weight of the piston.


(d)

Thermostatic bath preserved at temperature T compels its temperature (T) on the system.

System is enclosed in a frictionless piston and also cylinder exposed to an setting at push P.

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Thus, the press of the device must be equal to the press exerted on it and also ambient pressure by the weight of the piston.


(e)

If the valve in between two tanks is completely opened up for a brief period and also then closed, the pressure in the two tanks will be the very same as a result of press equilibrium.

If the initial temperature gradient connecting the two tanks is too massive, compared to a brief time while the valve is opened then the temperature would certainly not be the very same.

If the initial temperature gradient is comparatively tiny, so we may anticipate temperature equilibrium occurs after the valve is closed.


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Chemical, Biochemical, and also Engineering Thermodynamics (5th Edition) Edit edition

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