CHEMICAL BIOCHEMICAL AND ENGINEERING THERMODYNAMICS 4TH EDITION PDF

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(a)

Thermostatic bath (surroundings) kept at temperature T compels its temperature (T) on the device.

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So, the constraint placed in the equilibrium state of the device is temperature.


(b)

Volume of the device need to be continuous as it is enclosed in a constant-volume container.

Mechanical isolation requires no work-related flow and also thermal isolation implies no warm flow between the mechanism and also surroundings.

As such, power of the mechanism such as interior energy and enthalpy is additionally consistent.


(c)

There is no flow of warm because mechanism is thermally isolated from the surroundings.

Therefore, the press of the mechanism must be equal to the push exerted on it and also ambient press by the weight of the piston.


(d)

Thermostatic bath preserved at temperature T compels its temperature (T) on the system.

System is enclosed in a frictionmuch less piston and also cylinder exposed to an setting at push P.

See more: Foundations Of Materials Science And Engineering 5Th Edition

Because of this, the push of the system should be equal to the push exerted on it and ambient pressure by the weight of the piston.


(e)

If the valve between 2 tanks is completely opened up for a short duration and also then closed, the press in the two tanks will certainly be the same as a result of pressure equilibrium.

If the initial temperature gradient connecting the two tanks is as well significant, compared to a short time while the valve is opened up then the temperature would certainly not be the very same.

If the initial temperature gradient is comparatively small, so we may anticipate temperature equilibrium occurs after the valve is closed.


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Chemical, Biochemical, and Engineering Thermodynamics (fourth Edition) Edit edition

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